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Let Π be the set of all partitions of {1, 2, …, 2n} into pairs without regard to order. There are (2n − 1)!! such partitions. An element α ∈ Π, can be written as
with ik < jk. Let
be a corresponding permutation and let us define sgn(α) to be the signature of π. This depends only on the partition α and not on the particular choice of π.
Let A = {aij} be a 2n×2n antisymmetric matrix. Given a partition α as above define
We can then define the Pfaffian of A to be
The Pfaffian of a n×n skew-symmetric matrix for n odd is defined to be zero.
One can asociate to any antisymmetric 2n×2n matrix A ={aij} a bivector
where {e1, e2, …, e2n} is the standard basis of R2n. The Pfaffian is then defined by the equation
here ωn denotes the wedge product of n copies of ω with itself.
For a 2n × 2n skew-symmetric matrix A and an arbitrary 2n × 2n matrix B,
The Pfaffian is an invariant polynomial of a skew-symmetric matrix (Note that it is not invariant under a general change of basis but rather under a proper orthogonal transformation). As such, it is important in the theory of characteristic classes. In particular, it can be used to define the Euler class of a Riemannian manifold which is used in the generalized Gauss-Bonnet theorem.
The term Pfaffian was introduced by Arthur Cayley, who used the term in 1852: "The permutants of this class (from their connection with the researches of Pfaff on differential equations) I shall term Pfaffians." The term honors of German mathematician Johann Friedrich Pfaff .