Home > Palladium

rhodium – palladium – silver
Ni Pd Pt
	Full table

General

Name, Symbol, Number

palladium, Pd, 46

Chemical series

Transition metals

Group, Period, Block

10Group 10 Period 4 28 Ni 5 46 Pd 6 78 Pt 7 110 Ds The Group 10 elements are: Nickel (28) Palladium (46) Platinum (78) Darmstadtium (110) Key to color coding in table slice on right: Transition metals Color coding for these atomic numbers: At room temperatu, 5A period 5 element is one of the chemical elements in the fifth row (or period of the periodic table of the elements. These are: Chemical elements in the fifth period Group 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 #Name 37 Rb 38 Sr 39 Y 40 Zr 41 Nb 42 , dThe d-block of the periodic table of elements consists of those periodic table groups that contain elements in which, in the atomic ground state, the highest-energy electron is in a d- orbital. The d-block elements are often also known as transition metal

DensityFor other meanings of density, see density (disambiguation Density (symbol: rho Greek: rho) is a measure of mass per unit of volume. The higher an object's density, the higher its mass per volume. The average density of an object equals its total mass div, Hardness

12023 kg/m³Kilogram per cubic metre is the SI measure of density and is represented as kg/m³, where kg stands for kilogram and m³ stands for cubic metre. The density of water is about 1000 kg/m³, since a cubic metre of water weighs about a tonne. kg/m³" is sometimes, 4.75

AppearanceFor alternative meanings, see color (disambiguation). visual arts. Color (or colour is a sensation which (in humans) derives from the ability of the fine structure of the eye to distinguish three differently filtered analyses of a view. The perception of

Silvery white metallic

Atomic properties

Atomic weightIn reference to a certain isotope of a chemical element, atomic weight (more accurately relative atomic mass though also called simply atomic mass is the mass of one atom of the isotope expressed in units atomic mass unit amu) such that the Carbon-12 isot

106.42 u

Atomic radius (calc.)

140 (169) pm

Covalent radius

131 pm

van der Waals radius

163 pm

Electron configuration

[ Kr]4d¹⁰

e^- 's per energy level

2, 8, 18, 18, 0

Oxidation states ( Oxide)

±1 (mildly basic)

Crystal structure

Cubic face centered

Physical properties

State of matter

Solid ( __)

Melting point

1828.05 K (2830.82 ° F)

3236 K (5365 °F)

8.56 ×10^-6 m³/mol

357 kJ/mol

17.6 kJ/mol

1.33 Pa at 1825 K

3070 m/s at 293.15 K

Miscellaneous

Electronegativity

2.20 ( Pauling scale)

Specific heat capacity

244 J/(kg*K)

Electrical conductivity

9.5 10⁶/(m· ohm)

Thermal conductivity

71.8 W/(m*K)

1^st ionization potential

804.4 kJ/mol

2^nd ionization potential

1870 kJ/mol

3^rd ionization potential

3177 kJ/mol

Most stable isotopes

iso	NA	half-life	DM	DE M eV	DP
¹⁰²Pd	1.02%	Pd is stable with 56 neutrons
¹⁰⁴Pd	11.14%	Pd is stable with 58 neutrons
¹⁰⁵Pd	22.33%	Pd is stable with 59 neutrons
¹⁰⁶Pd	27.33%	Pd is stable with 60 neutrons
¹⁰⁷Pd	{syn.}	6.5 E6 y	β^-	0.033	¹⁰⁷ Ag
¹⁰⁸Pd	26.46%	Pd is stable with 62 neutrons
¹¹⁰Pd	11.72%	Pd is stable with 64 neutrons

SI units & STP are used except where noted.

Palladium is a chemical element with symbol Pd and atomic number 46. A rare silver-white transition metal of the platinum group, palladium resembles platinum chemically and is extracted from some copper and nickel ores. It is primarily used as an industrial catalyst and in jewelry.

1 Notable characteristics

Palladium is a soft steel-white metal that resembles platinum, doesn't tarnish in air, and is the least dense and has the lowest melting point of the platinum group metals. It is soft and ductile when annealed and greatly increases its strength and hardness when it is cold-worked. Palladium is chemically attacked by sulfuric and nitric acid but dissolves slowly in hydrochloric acid. This metal also does not react with oxygen at normal temperatures.

This metal has the uncommon ability to absorb up to 900 times its own volume of hydrogen at room temperatures. It is thought that this possibly forms palladium hydride - Pd₂H - but it is not yet clear if this is a true chemical compound.

Common oxidation states of palladium are +2, +3 and +4. Recently, palladium compounds in which palladium has oxidation state +6 were synthesized.

2 Applications

When it is finely divided, palladium forms a good catalyst and is used to speed up hydrogenation and dehydrogenation reactions, as well as in petroleum cracking. It is also alloyed and used in jewelry. Other uses;

White gold is an alloy of gold that is decolorized by the addition of palladium.
Similar to gold, palladium can be beaten into a thin leaf form as thin as 1/250,000 in.
Hydrogen easily diffuses through heated palladium; thus, it provides a means of purifying the gas.
Telecommunications switching-system equipment uses palladium.
Palladium is also used in dentistry, watchmaking , in aircraft spark plugs and in the production of surgical instrument s and electrical contacts.

3 History

Palladium was discovered by William Hyde Wollaston in 1803. This element was named by Wollaston in 1804 after the asteroid Pallas, which was discovered two years earlier.

Wollaston found element 46 in crude platinum ore from South America. He did this by dissolving the ore in aqua regia, neutralizing the solution with sodium hydroxide, Na OH, precipitating platinum as ammonium chloroplatinate through treatment with ammonium chloride, N H₄ Cl, and then adding mercuric cyanide to form the compound palladium cyanide . Finally, he heated the resulting compound in order to extract palladium metal.

The compound palladium chloride was at one time prescribed as a tuberculosis treatment at the rate of 0.065 g per day (approximately 1 mg per kg of body weight). This treatment did not have too many ill side effects but was later replaced by more effective drugs.

The element played an essential role in the Fleischmann-Pons experiment, also known as cold fusion.

4 Occurrence

Palladium is found as a free metal and alloyed with platinum and gold with platinum group metals in placer deposits of the Ural Mountains, Australia, Ethiopia, South and North America. However it is commercially produced from nickel- copper deposits found in South Africa and Ontario (the huge volume of ore processed makes this extraction profitable in spite of its low concentration in these ores).

5 Isotopes

Naturally-occurring palladium is composed of six isotopes. The most stable radioisotopes are Pd-107 with a half-life of 6.5 million years, Pd-103 with a half-life of 17 days, and Pd-100 with a half-life of 3.63 days. Eighteen other radioisotopes have been characterized with atomic weights ranging from 92.936 u (Pd-93) to 119.924 u (Pd-120). Most of these have half-lifes that are less than a half an hour except Pd-101 (half-life: 8.47 hours), Pd-109 (half-life: 13.7 hours), and Pd-112 (half-life: 21 hours).

The primary decay mode before the most abundant stable isotope, Pd-106, is electron capture and the primary mode after is beta decay. The primary decay product before Pd-106 is rhodium and the primary product after is silver.

Radiogenic Ag-107 is a decay product of Pd-107 and was first discovered in the Santa Clara, California meteorite of 1978. The discoverers suggest that the coalescence and differentiation of iron-cored small planets may have occurred 10 million years after a nucleosynthetic event. Pd-107 versus Ag correlations observed in bodies, which have clearly been melted since accretion of the solar system, must reflect the presence of short-lived nuclides in the early solar system.

6 References

Los Alamos National Laboratory – Palladium

7 External links

Chemical elements Metals

<Hide>

Topics: Palladium, Notable Characteristics, Applications, History...

PalladiumThis article describes the chemical element palladium. For other meanings, see palladium (disambiguation Palladium is a chemical element with symbol Pd and atomic number 46. A rare silver-white transition metal of the platinum group, palladium resembles p	Palladium (disambiguation)Originally, a palladium is a statue of anyone called Pallas . The word later assumed a variety of other meanings. The word is a Latinization of the Greek word παλλαδιον, which can be transliterated as "pa	Palladium hydridePalladium hydride is metallic palladium that contains a substantial quantity of hydrogen within its crystal lattice. At room temperature and atmospheric pressure, palladium can absorb up to 900 times its own volume of hydrogen. This remarkable property al
Palladium GamesFounded by Kevin Siembieda and Erick Wujcik, Palladium Games (also known as Palladium Books is a role-playing game publisher known most popularly for their best-selling, genre-crossing Rifts gaming series ( 1990-present). Although not created to be a univ	Palladium BooksRole playing Company, based in Taylor Michigan External Links .