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Rivero has appeared on the cover of publications such as Elle, Glamour and Vogue and is one of the select group of Victoria's Secret models known as the 'angels'.
Away from modelling, Rivero has also produced a musical album entitled Haste Siempre which contained a hit single about Argentine-born revolutionary Che Guevara.
She was previously married to French artist Alčs Basseville , who she divorced in 1998, and is now married to Miami-based Cuban financier Jorge Mora .