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Di Buo competed at the 2004 Summer Olympics in men's individual archery. He won his first match, advancing to the round of 32. In the second round of elimination, he was again victorious and advanced to the round of 16. The third match was di Buo's downfall, as he lost to fellow Italian and eventual gold medalist Marco Galiazzo. Di Buo placed 16th overall.
Di Buo was also a member of the 7th-place Italian men's archery team at the 2004 Summer Olympics.
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