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Psarra represented Greece at the 2004 Summer Olympics. She placed 8th in the women's individual ranking round with a 72-arrow score of 652. In the first round of elimination, she faced 57th-ranked Jo-Ann Galbraith of Australia. Psarra defeated Galbraith 138-116 in the 18-arrow match to advance to the round of 32. In that round, she faced 25th-ranked Turkish archer Zekiye Keskin Satir, defeating her 163-161. Psarra then defeated 24th-ranked Almudena Gallardo of Spain 160-152, advancing to the quarterfinals.
In the quarterfinals, Psarra faced Park Sung Hyun of Korea, losing to the 1st-ranked and eventual gold medalist archer. The final score of 111-110 in the 12 arrow match placed Psarra 7th overall in women's individual archery.
Psarra was also a member of the 5th-place Greek team in the women's team archery competition.
Psarra, Evangelia Psarra, Evangelia Psarra, Evangelia