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She is a two-times Olympic champion, having won gold in single sculls in 1996 Summer Olympics in Atlanta and 2000 Summer Olympics in Sydney. In 2004 Summer Olympics in Athens she won a silver medal.
Her maiden name is Khodotovitch (Ходотович), and she is also sometimes refered to as Ekaterina Karsten-Khodotovitch. Currently she lives and trains in Germany with her German husband in Potsdam.