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Modern air guns are typically low-powered, but high-powered designs have been used for hunting and military applications. They do benefit from very high accuracy, and are used in sharpshooting events in the Olympic Games.
There are many different types of air guns: spring-piston, multi-pump pneumatic, precharged pneumatic (PCP), and reservoir.
Spring-piston air guns achieve muzzle velocities near the speed of sound from a single, not-too-difficult cock.
Spring-piston guns operate by means of a spring-loaded piston in a chamber separate from the barrel. Cocking the gun compresses the spring; pulling the trigger releases it and causes the piston to drive air into the barrel.
As the air compresses, it becomes very hot, often in excess of 1000°C. (Because of the rapidity of the firing process, very little of this heat is lost into the gun's metal parts. Consequently, spring-piston guns are more efficent than reservoir guns.) Lubricants (such as molybdenum disulfide) are generally designed so that they burn gently at this temperature; upwards of 30% of the energy of the shot may come from this effect. On the other hand, excessively flammable lubricants may detonate and damage the gun.
Spring-piston guns seem to have a practical upper limit of 1200 ft/s (370 m/s) for .177 cal (4.5 mm) pellets.
Most spring piston guns are single shot breech loaders by nature (somewhat like an old shotgun) but multiple-shot guns have been increasingly common in recent years. Spring guns are typically cocked by a mechanism is which the gun is hinged at the mid-point, with the barrel serving as a cocking lever. Other systems used include side levers, under-barrel levers and motorized cocking, powered by a rechargeable battery.
Unlike cartridge firearms, the spring is very powerful in these guns and is held back by a sear that has a very small engagement area. There have been cases of severe crushing and even amputation when the spring has been released unexpectedly. Always use one hand to restrain the cocking lever when loading these guns so that should the sear slip, you will not be injured.
Spring guns, especially the higher powered ones, have a tendency vibrate/recoil quite a bit. Although this recoil is not comparable in magnitude to that of a cartridge firearm, it can make the gun difficult to shoot accurately as the vibration is well under way while the pellet is still in the barrel. Most guns seem to respond well to a light repeatable hold that allows the gun to vibrate the same way from shot to shot. Spring gun recoil also has a sharp forward component that is well known for breaking telescopic sights. On any but the lowest power spring guns, any telescope should be airgun rated. Spring gun tuning can reduce vibration to very low levels. Airgunsmiths specialize in airgun modifications.
The better quality spring air guns can have long service lives, often exceeding thirty years. Because they deliver the same energy on each shot, the trajectory is extremely repeatable. This repeatability resulted in most Olympic air gun matches through the 1970s and into the 1980s being short with spring-piston guns. Beginning in the 1980s, guns powered by compressed, liquefied carbon dioxide began to dominate competition. Today, the guns used at the highest levels of competition are powered by compressed air stored at very high pressures of 2000 to 3000 lb/in² (14 to 21 MPa).
The Chinese army uses spring-piston small arms to train more economically. Surplus military-issue Chinese spring-piston air-guns are sometimes widely available by mail-order.
The typical projectile used in rifled airguns is the lead diablo pellet. This is a wasp-wasted projectile open at the base and having a variety of head styles. The diablo pellet is designed to be drag stabilized. This, in addition to the spin afforded by the rifling, makes the airgun one of the most accurate of all guns. Another advantage of the diablo pellet it that the high drag produces short maximum ranges which adds to safety. The diablo pellet is not a stable as some other shapes in the transonic region. While some high power spring guns can propel light pellets at or beyond the speed of sound, this results in decreased accuracy and often decreased life of the spring and seals (the low momentum of the light pellet causing it to start moving down the barrel before maximum pressure is reached resulting in loss of the air cushion and subsequent slamming of the piston/seal into the end of the chamber at high velocity.)
Most spring-piston air guns have a calibre of .177 (4.5 mm), and are designed for target practice. Cost per round is less than $0.02 (US) for Olympic-quality ammunition, and far less for cheaper grades. .20 .22 and .25 calibre (~5.1, ~5.6 and ~6.4 mm) guns exist, and are used mainly for hunting and field target shooting.